Enantioselective Henry reaction catalyzed by a novel L-(+)-aspartic acid-derived Schiff base ligand and Cu(II) ion

KOZ G., ASTLEY D. , ASTLEY S. T.

TURKISH JOURNAL OF CHEMISTRY, cilt.35, ss.553-560, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 35 Konu: 4
  • Basım Tarihi: 2011
  • Doi Numarası: 10.3906/kim-1103-19
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.553-560

Özet

Mild and efficient enantioselective Henry reactions of nitromethane with various aldehydes were catalyzed by a novel L-(+)-aspartic acid-derived Schiff base ligand in the presence of Cu(II) ions, affording the corresponding adducts in high yields (up to 96%) and enantioselectivities (up to 92% ee).