Synthesis, structure, and electrochemical properties of N,N '-bis(ferrocenylmethylene) ethylenediamine Schiff base and its metal complexes


akcan kardaş t., AVCI ÖZBEK H., AKGÜL Y. , DEMİRHAN F.

INORGANIC AND NANO-METAL CHEMISTRY, cilt.47, ss.1475-1479, 2017 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 47 Konu: 10
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1080/24701556.2017.1357586
  • Dergi Adı: INORGANIC AND NANO-METAL CHEMISTRY
  • Sayfa Sayısı: ss.1475-1479

Özet

The reaction of N,N '-bis(ferrocenylmethylene)ethylenediamine (FcNN) Schiff base with metal salts gave SnCl(4)FcNN (1), SnCl(2)FcNN(H2O)(2) (2), Sn-2(CH3)(4)Cl(4)FcNN (3), Ti(2)Cl(8)FcNN (4), CdFcNN(NO3)(2) (5), and CuFcNN(NO3)(2) (6). New complexes (1)-(6) were characterized by IR and elemental analysis techniques. IR spectra showed that the Schiff base was coordinated to the metal ions in a bidentate manner with N,N' donor sites. The H-1 NMR spectra of complexes (1), (2), and (4) show all the expected signals with a typical signal pattern of disubstituted ferrocenyl groups. The electrochemical properties of complexes were determined by cyclic voltammetry. Cyclic voltammetry results show that these complexes exhibit one irreversible oxidation peak.