Synthesis and Characterization of Functional Acrylic Copolymers via RAFT Mini-Emulsion Polymerization


Creative Commons License

YILMAZ O. , Ozkan C. K. , YILMAZ C. N. , YORGANCIOĞLU A. , ÖZGÜNAY H. , KARAVANA H. A.

International Conference on Environment, Chemical Engineering and Materials (ECEM), Brasov, Romanya, 27 - 29 Haziran 2017, cilt.1918 identifier identifier

  • Cilt numarası: 1918
  • Doi Numarası: 10.1063/1.5018501
  • Basıldığı Şehir: Brasov
  • Basıldığı Ülke: Romanya

Özet

Copolymers bearing reactive functional groups with controlled molecular weights are of importance since they can be used in many fields such as composites, coatings, membranes, catalysis, biology, optoelectronics, pharmaceuticals, etc. In the present study low molecular weight copolymers based on butyl acrylate (BA) and methyl methacrylate (MMA) in combination with reactive functional monomers of vinyl trietoxysilane (VTES), 3-trimetoxysilylpropyl methacrylate (TMSPMA) and glycidyl methacrylate (GMA) were synthesized via RAFT mini emulsion technique using 2-cyano 2-propyldodecyldithiocarbonate as CTA agent. The results showed that the average molecular weights of copolymers were close to the theoretical values. On the other hand, PDI values were found to be higher than conventional RAFT polymers. The particle sizes of the latexes were small with very homogenous distributions and good stability. FTIR, H-NMR and TGA results verified the success of copolymer syntheses.