Reactions of the solvent-stabilized compound [MoOCl2(THF)(2)] with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1*calculations


Kilickaya G., Dogan B., Acar N. , Sozuer I. T.

TURKISH JOURNAL OF CHEMISTRY, cilt.33, ss.693-708, 2009 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 33 Konu: 5
  • Basım Tarihi: 2009
  • Doi Numarası: 10.3906/kim-0812-73
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.693-708

Özet

Reaction of the solvent-stabilized dioxo-molybdenum(VI) compound [MoO2Cl2(THF)(2)] with PPh3 yielded the oxomolybdenum(IV) species [MoOCl2(THF)(2)] (1) by the removal of one oxygen atom as PPh3O. The complexes [MoOCl2(=NC6H4CN)] 2, [MoOCl2(CNC6H4OH)] 3, [MoOCl2(=NC6H4NH2)] 4, and [MoOCl2(=NC6H4OCH3)] 5, were synthesized by the reactions of [MoOCl2(THF)(2)] with XC6H4Y (X = NH2, Y = CN; X = CN, Y = OH; X = Y = NH2; X = NH2, Y = OCH3). All the new compounds were characterized by elemental analyses, and FTIR, UV-Vis, and H-1- and C-13-NMR spectra. Geometrical parameters and molecular orbital calculations showed that compounds 2-5 are stabilized by a charge transfer between the Mo center and the phenyl ring.