Heterogeneous Fenton-like Degradation of Orange II in Water Using FeZSM-5 Zeolite Catalyst


Bolova E., Gündüz G., Dükkancı M.

INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, cilt.10, 2012 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 10
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1515/1542-6580.2852
  • Dergi Adı: INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING

Özet

In this study, Fenton-like degradation of Orange II in water was investigated over an FeZSM-5 zeolite catalyst prepared by ion exchange. A color removal of 99.99% and a COD elimination of 55.0% were achieved after a reaction time of 2h at 266.7 mM H2O2 at 323 K for 0.05 g/dm3 of Orange II solution at a pH around 7. Initial decolorization rate was described by an equation of -rAo = 6.4x103 e-30.7/RT COII, o CH2O2,o0.3 where R is in kJ/mol. No significant decay in decolorization efficiency of the used catalyst was observed.