FT-IR spectroscopic investigation of some Hofmann type complexes: M(2-(1-Cyclohexenyl)ethylamine)(2)Ni(CN)(4) (M = Ni, Co)


İZGİ T., Parlak C. , Aytekin T., Senyel M.

JOURNAL OF MOLECULAR STRUCTURE, vol.892, pp.311-315, 2008 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 892
  • Publication Date: 2008
  • Doi Number: 10.1016/j.molstruc.2008.05.041
  • Title of Journal : JOURNAL OF MOLECULAR STRUCTURE
  • Page Numbers: pp.311-315

Abstract

New Hofmann type complexes in the form of M(CyHEA)(2)Ni(CN)(4) (where CyHEA = 2-(1-cyclohexenyl)ethylamine; M = Ni or Co) have been prepared in powder form and their infrared spectra have been reported in the range of 4000-400 cm(-1). The thermal behaviour of these complexes has been investigated by differential thermal analysis (DTA) and thermo-gravimetric analysis (TGA). The results suggest that these compounds are similar in structure to Hofmann type complexes and their structures consist of polymeric layers vertical bar M-Ni(CN)(4)vertical bar(infinity) with the CyHEA molecule bound to the metal atom (M). (C) 2008 Published by Elsevier B.V.