[Bis(diphenylphosphino)amine-kappa P-2,P '][1,3-bis(diphenylphosphino)propane-kappa P-2,P ']platinum(II) dichloride dichloromethane solvate

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Irisli S. , SEN A.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.61, 2005 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 61
  • Publication Date: 2005
  • Doi Number: 10.1107/s1600536805029880
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Abstract

The title complex, [ Pt( C24H21NP2)( C27H26P2)] Cl-2 center dot CH2Cl2 or [ Pt( dppa)( dppp)] Cl-2 center dot CH2Cl2, where dppa is bis( diphenylphosphino) amine and dppp is 1,3-bis( diphenylphosphino) propane, has two different chelate rings. The Pt II atom has a distorted square-planar geometry. The six-membered chelate ring of dppp has a chair conformation. There is a hydrogen bond between the dppa N - H group and a Cl- counter-ion.