FT-IR and Raman spectroscopic analysis of some Hofmann type complexes


Parlak C.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.99, ss.12-17, 2012 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 99
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1016/j.saa.2012.09.020
  • Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Sayfa Sayıları: ss.12-17

Özet

Some new Hofmann type complexes with chemical formula of M(4pypp)(2)Ni(CN)(4) (where 4pypp = 4-(1-pyrrolidinyl)piperidine and M=Ni or Co) were prepared and their FT-IR and Raman spectra were reported in the region of 4000-200 cm(-1) and 4000-100 cm(-1), respectively. The ligand molecule, polymeric sheet and metal-ligand bands of the compounds were assigned in detail. Vibrational spectra together with assignments of 4pypp (C9H18N2) were experimentally and theoretically studied in the region of 400-100 cm(-1). Normal mode frequencies and corresponding vibrational assignments of Ni(CN)(4)(2-) were theoretically examined by standard quantum chemical technique. Reliable vibrational assignments were made on the basis of potential energy distribution (PED) analysis. The results suggest that these compounds are similar in structure to the Hofmann type complexes and the 4phpy ligand molecule bonds to the metal (M) atom of vertical bar M-Ni(CN)(4)vertical bar(infinity) polymeric layers. (c) 2012 Elsevier B.V. All rights reserved.