Palladium-catalysed reactions of conjugated enyne oxiranes with organoborons: A diastereoselective method of the synthesis of 2,4,5-trienol derivatives


Ziyanak F., Kus M., Alkan-Karadeniz L. , Artok L.

TETRAHEDRON, vol.74, no.27, pp.3652-3662, 2018 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 74 Issue: 27
  • Publication Date: 2018
  • Doi Number: 10.1016/j.tet.2018.05.030
  • Title of Journal : TETRAHEDRON
  • Page Numbers: pp.3652-3662

Abstract

A palladium-catalysed reaction of conjugated enyne oxiranes with organoboron reagents is described. This method allows aryl-substituted vinylallenes containing a hydroxyl group on the allylic position to be synthesized, with good diastereomeric ratios, under mild conditions. (C) 2018 Elsevier Ltd. All rights reserved.