Tridentate ligands derived from L-tert-Leucine for the Cu(II) mediated asymmetric Henry reaction


Korkmaz N., ASTLEY D. , ASTLEY S. T.

TURKISH JOURNAL OF CHEMISTRY, vol.35, no.3, pp.361-374, 2011 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 35 Issue: 3
  • Publication Date: 2011
  • Doi Number: 10.3906/kim-1009-15
  • Title of Journal : TURKISH JOURNAL OF CHEMISTRY
  • Page Numbers: pp.361-374

Abstract

Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions. Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired beta-nitroalcohols were obtained.