Tridentate ligands derived from L-tert-Leucine for the Cu(II) mediated asymmetric Henry reaction


Korkmaz N., ASTLEY D. , ASTLEY S. T.

TURKISH JOURNAL OF CHEMISTRY, cilt.35, ss.361-374, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 35 Konu: 3
  • Basım Tarihi: 2011
  • Doi Numarası: 10.3906/kim-1009-15
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.361-374

Özet

Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions. Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired beta-nitroalcohols were obtained.