New Cu(II) coordination polymer by chiral tridentate Schiff base ligand


MESSAI A., BILGE D., BİLGE M., PARLAK C.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1137, ss.349-353, 2017 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 1137
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1016/j.molstruc.2017.02.046
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Sayfa Sayıları: ss.349-353

Özet

The present research reports the synthesis, X-ray, magnetic and electronic properties for novel coordination polymer based upon copper (II) with chiral tridentate Schiff base ligand synthesized at condensation of acetylacetone and L-leucine amino acid. The investigation was also conducted by quantum mechanical calculations. The large energy gap indicates a high kinetic stability. Magnetic measurement gives predominant antiferromagnetic interactions within the chain. Results reveals further insight into copper(II) chiral tridentate Schiff base complexes. (C) 2017 Elsevier B.V. All rights reserved.