VIBRATIONAL SPECTROSCOPIC INVESTIGATION OF SOME HOFMANN TYPE CLATHRATES: M(4-PHENYLPYRIDINE)(2)Ni(CN)(4)center dot 2G (M = Ni, Co AND Cd, G=1,4-DIOXANE)


Parlak C.

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, vol.24, no.3, pp.375-381, 2010 (Journal Indexed in SCI) identifier

  • Publication Type: Article / Article
  • Volume: 24 Issue: 3
  • Publication Date: 2010
  • Title of Journal : BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA
  • Page Numbers: pp.375-381

Abstract

New Hofmann type clathrates in the form of M(4-Phpy)(2)Ni(CN)(4)center dot 2G (where 4-Phpy = 4-phenylpyridine, G = 1,4-dioxane and M = Ni, Co and Cd) have been prepared in powder form and their FT-IR and Raman spectra have been reported. The results suggest that these compounds are similar in structure to the Hofmann type clathrates and their structures consist of polymeric layers of vertical bar M-Ni(CN)(4)vertical bar(infinity) with the 4-Phpy bound to the metal (M) atom.