COORDINATION OF COPPER AND SILVER BY [CO2(MU-C2(CH2SCH2CH2)2S)(CO)6]


DEMIRHAN F., IRISLI S. , SALEK S., SENTURK O., WENT M., JEFFERY J.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.453, 1993 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 453 Konu: 2
  • Basım Tarihi: 1993
  • Doi Numarası: 10.1016/0022-328x(93)83134-h
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY

Özet

The thiamacrocycle [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine substitution.