Preparation Of A Chiral Cu(II)-Schiff Base Complex And Application For Asymmetric Catalysis


Alkan L. , Astley S. T.

Karaelmas Fen ve Mühendislik Dergisi, cilt.8, ss.151-155, 2018 (Diğer Kurumların Hakemli Dergileri)

  • Cilt numarası: 8
  • Basım Tarihi: 2018
  • Dergi Adı: Karaelmas Fen ve Mühendislik Dergisi
  • Sayfa Sayıları: ss.151-155

Özet

A chiral copper(II)-Schiff base complex was synthesized from L-Phenylalanine for the enantioselective Henry reaction. A variety

of chiral β-nitroalcohols were obtained in good yield (up to 76%) with high enantioselectivities (up to 90% ee) under the optimized

reaction conditions.