The metal-halogen exchange reaction between ortho-substituted aryl halides and Ph2CuLi center dot LiCN: scope and applicability for coupling reactions

Cetin, FATMA; Senogul, HB; Gezer, S; Astley, D; Astley, STEPHEN

doi:10.1016/j.jorganchem.2003.09.043

The metal-halogen exchange reaction between ortho-substituted aryl halides and Ph2CuLi center dot LiCN: scope and applicability for coupling reactions

Atıf İçin Kopyala

Cetin F. , Senogul H., Gezer S., Astley D., Astley S. T.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.689, ss.154-157, 2004 (SCI İndekslerine Giren Dergi)

Cilt numarası: 689 Konu: 1
Basım Tarihi: 2004
Doi Numarası: 10.1016/j.jorganchem.2003.09.043
Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
Sayfa Sayıları: ss.154-157

Özet

Metal-halogen exchange between Ph2CuLi . LiCN and ortho-substituted aryl iodides or bromides may be used to conveniently afford substituted metallated aryls which can subsequently undergo reaction with electrophiles. (C) 2003 Elsevier B.V. All rights reserved.