Vibrational spectroscopic study on some Hofmann type clathrates: M(2-(1-cyclohexenyl)ethylamine)(2)Ni(CN)(4)center dot 2benzene (M = Ni and Cd)


İZGİ T., Parlak C. , Senyel M.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.79, ss.308-311, 2011 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 79 Konu: 2
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.saa.2010.12.044
  • Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Sayfa Sayıları: ss.308-311

Özet

New Hofmann type benzene clathrates in the form of M(CyHEA)(2)Ni(CN)(4)center dot 2benzene (where CyHEA= 2-(1-cyclohexenyl)ethylamine and M=Ni or Cd) have been prepared in powder form and FT-IR and Raman spectra have been reported. The results suggest that title compounds are similar in structure to Hofmann type clathrates and their structures consist of polymeric layers of vertical bar M-Ni(CN)(4)vertical bar(infinity) with the CyHEA molecule bounded to the metal atoms (M). (C) 2011 Published by Elsevier B.V.