A Fluorimetric Method Based On Magnetic Molecularly Imprinted Polymer For Selective Detection Of Chlorferon


İLKTAÇ R.

JOURNAL OF FLUORESCENCE, 2021 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Publication Date: 2021
  • Doi Number: 10.1007/s10895-021-02857-3
  • Title of Journal : JOURNAL OF FLUORESCENCE
  • Keywords: Chlorferon, Pesticide metabolite, Magnetic molecularly imprinted polymer, Fluorimetric determination, COUMAPHOS, DIETHYLTHIOPHOSPHATE, ANTIOXIDANT, EXTRACTION, GREEN, ION, OIL

Abstract

In the present work, reusable magnetic molecularly imprinted polymers have been used for the first time as an adsorbent for the determination of chlorferon. Magnetic molecularly imprinted polymers have been used for the selective separation of chlorferon from the solution and sensitive fluorimetric determination has been performed using the native fluorescence of chlorferon. The developed method is rapid and determination of chlorferon was completed in an hour. Limit of detection (LOD) of the method was found to be 0.0027 mu M and the linearity of the calibration graph was observed within the range of 0.01-0.36 mu M (2.5 - 75 mu g L-1). Adsorption isotherms point out the multilayer adsorption and the heterogeneous distribution of binding sites for imprinted polymer and homogeneous binding site for non-imprinted polymer. The adsorption capacities of imprinted polymer and non-imprinted polymer were calculated as 2.03 mu mol g(-1) and 0.96 mu mol g(-1), respectively and the imprinting factor was found to be 2.11. The interference effects of some organic compounds and characterization studies were also evaluated. The method has been applied to honey and tap water samples and the recoveries were found to be in the range of 91.3 and 101.1 %.