[Bis(diphenylphosphino)methane-kappa P-2,P '][bis(diphenylthiophosphinyl)methane-kappa S-2,S ']-platinum(II) bis(perchlorate) acetone solvate


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ALKAN L. , Irisli S.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.61, 2005 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 61
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1107/s1600536805038304
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

Özet

The title complex, [Pt(C25H22P2)(C25H22P2S2)](ClO4)(2)center dot C3H6O or [Pt(dppm)(dppmS(2))](ClO4)(2)center dot C3H6O, where dppmS(2) is bis(diphenylthiophosphinyl) methane and dppm is bis( diphenylphosphino) methane, is the first example of a platinum(II) complex containing both dppm and dppmS(2) ligands. In the cation, the dppm ligand forms a non-planar four-membered chelate ring, while the dppmS(2) ligand forms a six-membered chelate ring with twist-boat conformation.