Synthesis of 2-aminomethylpiperidine ruthenium(II) phosphine complexes and their applications in transfer hydrogenation of aryl ketones


Turkmen H.

APPLIED ORGANOMETALLIC CHEMISTRY, cilt.26, ss.731-735, 2012 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 26 Konu: 12
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1002/aoc.2924
  • Dergi Adı: APPLIED ORGANOMETALLIC CHEMISTRY
  • Sayfa Sayıları: ss.731-735

Özet

The complex trans,cis-[RuCl2(PPh3)2(ampi)] (2) was prepared by reaction of RuCl2(PPh3)3 with 2-aminomethylpiperidine(ampi) (1). [RuCl2(PPh2(CH2)nPPh2)(ampi) (n?=?3, 4, 5)] (35) were synthesized by displacement of two PPh3 with chelating phosphine ligands. All complexes (25) were characterized by 1?H, 13C, 31P NMR, IR and UV-visible spectroscopy and elemental analysis. They were found to be efficient catalysts for transfer hydrogen reactions. Copyright (C) 2012 John Wiley & Sons, Ltd.