Synthesis, X-ray Structural and Thermal Analysis of a Novel Copper Compound Containing Dissymmetric Independent 5-and 6-coordinate CuL(H2O)(n) (n=2, 3) Units and Hydrogen bond Bridges


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Barut D., KORKMAZ n., Astley S. T. , Aygun M.

ACTA CHIMICA SLOVENICA, vol.62, no.1, pp.88-94, 2015 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 62 Issue: 1
  • Publication Date: 2015
  • Doi Number: 10.17344/acsi.2014.734
  • Title of Journal : ACTA CHIMICA SLOVENICA
  • Page Numbers: pp.88-94

Abstract

The synthesis, thermogravimetric and X-ray structure analysis of a highly unusual copper compound prepared from a chiral tridentate Schiff base ligand is reported. The title compound [CuL(H2O) 2] center dot [ CuL(H2O) 3] center dot H2O crystallizes in the orthorhombic crystal system in space group P2(1)2(1)2(1) with Z = 4. The two independent CuL(H2O)(n) complexes are present in the same unit cell, along with an uncoordinated water molecule. The five-coordinated copper(II) centre occupies a distorted square-pyramidal geometry whereas the six-coordinated copper(II) centre has a distorted octahedral geometry. The independent copper complexes and the uncoordinated water molecule are joined together with intermolecular hydrogen bonds in a two-dimensional supramolecular network which lies parallel to the ab plane.